"Freon" is a Dupont trademark for hydrocarbons where some number of the
hydrogen atoms have been replaced with fluorine, chlorine and/or bromine.
The naming rules (e.g., Freon 12, Freon 134a etc.) are a bit complicated,
but the formula for most can be arrived at by adding 90 to the number and
noting that the resulting number interpreted as follows: first digit is the
number of carbons, second digit is the number of hydrogens and the third
digit the number of fluorines. The number of chlorines is gotten by taking
the difference between the sum of the number of hydrogens + fluorines and
substracting from the total number of available bonds to carbon. E.g.,
Freon 12 gives 102 as the number, which is 1 C, 0 H, 2 F and 2 Cl (4-2 since
C has four bonds available). So, Freon 12 is CCl2F2 or
dichlorodifluoromethane. 134a gives 224, so 2 C, 2H and 4F--only 6 bonds
available since the C are bonded to each other--so Freon 134a is C2H2F4.
The 'a' has to do with exactly how the F's and H's are bonded to the C's
("isomers").
That's the simplified version--a lot of words but pretty easy when you get
the hang of it (assuming you've any reason to want to get the hang of it!).
So--134a is still a "Freon", just not the one with which most are familiar.